Quartz-Porphyry
QUARTZ-PORPHYRY, in petrology, the name given to a group of hemi-crystalline acid rocks containing porphyritic crystals of quartz in a more fine-grained matrix which is usually of micro-crystalline or felsitic structure. In the hand specimens the quartz appears as small rounded, clear, greyish, vitreous blebs, which are crystals (double hexagonal pyramids) with their edges and corners rounded by resorption or corrosion. Under the microscope they are often seen to contain rounded enclosures of the ground-mass or fluid cavities, which are frequently negative crystals with regular outlines resembling those of perfect quartz crystals. Many of the latter contain liquid carbonic acid and a bubble of gas which may exhibit vibratile motion under high magnifying powers. In addition to quartz there are usually phenocrysts of felspar, mostly orthoclase, though a varying amount of plagioclase is often present. The felspars are usually full and cloudy from the formation of secondary kaolin and muscovite throughout their substance. Their crystals are larger than those of quartz and sometimes attain a length of two inches. Not uncommonly scales of biotite are visible in the specimens, being hexagonal plates, which may be weathered into a mixture of chlorite and epidote. Other porphyritic minerals are few, but hornblende, augite and bronzite are sometimes found, and garnet cordierite and muscovite may also occur. The garnets are small, of rounded shape and red or brownish colour; in some cases they appear to have been corroded or absorbed. Cordierite forms six-sided prisms with flat ends; these divide, between crossed nicols, into six triangular areas radiating from a centre, as the crystals, which belong to the rhombic system, are not simple but consist of three twins interpenetrating and crossing. In the vast majority of cases the cordierite has weathered to an aggregate of scaly chlorite and muscovite; this is known as pinite and is of dark green colour and very soft. The quartzporphyries or elvans which occur as dikes in Cornwall and Devon frequently contain this mineral. The augite and hornblende of these rocks are in most cases green, and are frequently decomposed into chlorite, but even then can usually be identified by their shape. A colourless rhombic pyroxene (enstatite or bronzite) occurs in a limited number of the rocks of this group and readily weathers to bastite. Apatite, magnetite, and zircon, all in small but frequently perfect crystals, are almost universal minerals of the quartz-porphyries.
The ground-mass is finely crystalline and to the unaided eye has usually a dull aspect resembling common earthenware; it is grey, green, reddish or white. Often it is streaked or banded by fluxion during cooling, but as a rule these rocks are not vesicular. Two main types may be recognized by means of the microscope-^the felsitic and the microcrystalline. In the former the ingredients are so fine-grained that in the thinnest slices they cannot be determined by means of the microscope. Some of these rocks show perlitic or spherulitic structure, and such rocks were probably originally glassy (obsidians or pitchstones), but by lapse of time and processes of alteration have slowly passed into very finely crystalline state. This change is called devitrification; it is common in glasses, as these are essentially unstable. A large number of the finer quartz-porphyries are also in some degree silicified or impregnated by quartz, chalcedony and opal, derived from the silica set free by decomposition (kaolinization) of the original felspar. This re-deposited silica forms veins and patches of indefinite shape or may bodily replace a considerable area of the rock by metasomatic substitution. The opal is amorphous, the chalcedony finely crystalline and often arranged in spherulitic growths which yield an excellent black cross in polarized light. The microcrystalline ground-masses are those which can be resolved into their component minerals in thin slices by use of the microscope. They prove to consist essentially of quartz and felspars, which are often in grains of quite irregular shape (microgranitic). In other cases these two minerals are in graphic intergrowth, often forming radiate growths of spherulites consisting of fibres of extreme tenuity; this type is known as granophyric. There is another group in which the matrix contains small rounded or shapeless patches of quartz in which many rectangular felspars are embedded; this structure is called micropoikilitic, and though often primary is sometimes developed by secondary changes which involve the deposit of new quartz in the ground-mass. As a whole those quartz-porphyries which have microcrystalline ground-masses are rocks of intrusive origin. Elvan is a name given locally to the quartz-porphyries which occur as dikes in Cornwall; in many of them the matrix contains scales of colourless muscovite or minute needles of blue Tourmaline. Fluorite and kaolin appear also in these rocks, and the whole of these minerals are due to pneumatolytic action by vapours permeating the porphyry after it had consolidated but probably before it had entirely cooled.
Many ancient rhyolitic quartz-porphyries show on their weathered surfaces numerous globular projections. They may be several inches in diameter, and vary from this size down to a minute fraction of an inch. When struck with a hammer they may detach readily from the matrix as if their margins were defined by a fissure. If they are broken across their inner portions are often seen to be filled with secondary quartz, chalcedony or agate: some of them have a central cavity, often with deposits of quartz crystals; they also frequently exhibit a succession of rounded cracks or dark lines occupied by secondary products. Rocks having these structures are common in N. Wales and Cumberland; they occur also in Jersey, the Vosges and Hungary. It has been proposed to call them pyromerides. Much discussion has taken place regarding the origin of these spheroids, but it is generally admitted that most of them were originally spherulites, and that they have suffered extensive changes through decomposition and silicification.
Many of tjie older quartz-porphyries which occur in Palaeozoic and Pre-Cambrian rocks have been affected by earth movements and have experienced crushing and shearing. In this way they become schistose, and from their felspar minute plates of sericitic white mica are developed, giving the rock in some cases very much of the appearance of mica-schists. If there have been no phenocrysts in the original rock, very perfect mica-schists may be produced, which can hardly be distinguished from sedimentary schists, though chemically somewhat different on account of the larger amounts of alkalis which igneous rocks contain. When phenocrysts were present they often remain, though rounded and dragged apart while the matrix flows around them. The glassy or felsitic enclosures in the quartz are then very suggestive of an igneous origin for the rock. Such porphyry-schists have been called porphyroids or porphyroid-schists, and in America the name aporhyolite has been used for them. They are well known in some parts of the Alps, Westphalia, Charnwood (England), and Pennsylvania. The h&lleflintas of Sweden are also in part acid igneous rocks with a well-banded schistose or granulitic texture.
The quartz-porphyries are distinguished from the rhyolites by being either intrusive rocks or Palaeozoic lavas. All Tertiary acid lavas are included under rhyolites. The intrusive quartzporphyries are equally well described as granite-porphyries. The palaeozoic effusive quartz-porphyries (or acid lavas) would be called rhyolites by many English petrologists, who regard geological age as of no importance in petrological classifications. But the name quartz-porphyry, though somewhat ambiguous, is so expressive and so firmly established by long-continued use that it cannot be discarded, especially as a descriptive name for the use of field geologists. (J. S. F.)
Note - this article incorporates content from Encyclopaedia Britannica, Eleventh Edition, (1910-1911)
