Goniometer
GONIOMETER (from Gr. yuvla, angle, and fikrpov, measure), an instrument for measuring the angles of crystals; there are two kinds the contact goniometer and the reflecting goniometer. Nicolaus Stena in 1669 determined the interfacial angles of quartz crystals by cutting sections perpendicular to the edges, the plane angles of the sections being then the angles between the faces which are perpendicular to the sections. The earliest instrument was the contact goniometer devised by Carangeot in 1783. The Contact Goniometer (or Hand-Goniometer). This consists of two metal rules pivoted together at the centre of a graduated semicircle (fig. i). The instrument is placed with its plane perpendicular to an edge between two faces of the crystal to be measured, and the rules are brought into contact with the faces; this is best done by holding the crystal up against the light with the edge in the line of sight. The angle between the rules, as read on the graduated semicircle, then gives the angle between the two faces. The FIG. i. Contact Goniometer.
rules are slotted, so that they may be shortened and their tips applied to a crystal partly embedded in its matrix. The instrument represented in fig. i is practically the same in all its details as that made for Carangeot, and it is employed at the present day for the approximate measurement of large crystals with dull and rough faces. S. L. Penfield (1900) has devised some cheap and simple forms of contact goniometer, consisting of jointed arms and protractors made of cardboard or celluloid.
The Reflecting Goniometer. This is an instrument of far greater precision, and is always used for the accurate measurement of the angles when small crystals with bright faces are available. As a rule, the smaller the crystal the more even are its faces, and when these are smooth and bright they reflect sharply defined images of a bright object. By turning the crystal about an axis parallel to the edge between two faces, the image reflected from a second face may be brought into the same position as that formerly occupied by the image reflected from the first face; the angle through which the crystal has been rotated, as determined by a graduated circle to which the crystal is fixed, is the angle between the normals to the two faces.
Several forms of instruments depending on this principle have been devised, the earliest being the vertical-circle goniometer of W. H. Wollaston, made in 1809. This consists of a circle m (fig. 2), graduated to degrees of arc and reading with the vernier h to minutes, which turns with the milled head t about a horizontal axis. The crystal is attached _ with wax (a mixture of bees- FIG - 2. Vertical-Circle Goniometer, wax and pitch) to the holder q, and by means of the pivoted arcs it may be adjusted so that the edge between two faces (a zone-axis) is parallel to, and coincident with, the axis of the instrument. The crystal-holder and adjustmentarcs, together with the milled head s, are carried on an axis which passes through the hollow axis of the graduated circle, and may thus be rotated independently of the circle. In use, the goniometer is placed directly opposite to a window, with its axis parallel to the horizontal window-bars, and as far distant as possible. The eye is placed quite close to the crystal, and the image of an upper windowbar (or better still a slit in a dark screen) as seen in the crystal-face is made to coincide with a lower window-bar (or chalk mark on the floor) as seen directly: this is done by turning the milled head s, the reading of the graduated circle having previously been observed. Without moving the eye, the milled head /, together with the crystal, is then rotated until the image from a second face is brought into the same position; the difference between the first and second readings of the graduated circle will then give the angle between the normals of the two faces.
Several improvements have been made on Wollaston's goniometer. The adjustment-arcs have been modified; a mirror of black glass fixed to the stand beneath the crystal gives a reflected image of the signal, with which the reflec- . C T tion from the **^-*^ crystal can be more conveniently made to coincide; a telescope provided with cross-wires gives greater precision to the direction of the reflected rays of light; and with the telescope a collimator has sometimes been used. P A still greater improvement was effected by placing the graduated circle in a horizontal position, as in the instruments of E. L. Malus (1810), F.
FIG. 3. Horizontal-Circle Goniometer.
C. von Riese (1829) and J. Babinet (1839). Many forms of the horizontal-circle goniometer have been constructed; they are provided with a telescope and collimator, and in construction are essentially the same as a spectrometer, with the addition of arrangements for adjusting and centring the crystal. The instrument shown in fig. 3 is made by R. Fuess of Berlin. It has four concentric axes, which enable the crystal-holder A, together with the adjustmentarcs B and centring-slides D, to be raised or lowered, or to be rotated independently of the circle H; further, either the crystal-holder or the telescope T may be rotated with the circle, while the other remains fixed. The crystal is placed on the holder and adjusted so that the edge (zone-axis) between two faces is coincident with the axis of the instrument. Light from an incandescent gas-burner passes through the slit of the collimator C, and the image of the slit (signal) reflected from the crystal face is viewed in the telescope. The clamp o and slow-motion screw F enable the image to be brought exactly on the cross-wires of the telescope, and the position of the circle with respect to the vernier is read through the lens. The crystal and the circle are then rotated together until the image from a second face is brought on the cross-wires of the telescope, and the angle through which they have been turned is the angle between the normals to the two faces. While measuring the angles between the faces of crystals the telescope remains fixed by the clamp 0, but when this is released the instrument may be used as a spectrometer or refractometer for determining, by the method of minimum deviation, the indices of refraction of an artificially cut prism or of a transparent crystal when the faces are suitably inclined to one another. . .
With a one-circle goniometer, such as is described above, it is necessary to mount and re-adjust the crystal afresh for the measurement of each zone of faces (i.e. each set of faces intersecting in parallel edges) ; with very small crystals this operation takes a considerable time, and the minute faces are not readily identified again. Further, in certain cases, it is not possible to measure the angles between zones, nor to determine the position of small faces which do not lie in prominent zones on the crystal. These difficulties have been overcome by the use of a two-circle goniometer or theodolite-goniometer? which as a combination of a vertical-circle goniometer and one with a horizontal-circle was first employed by W. H. Miller in 1874. Special forms have been designed by E. S. Fedorov (1889), V. Gpldschmidt (1893), S. Czapski (1893) and F. Stoeber (1898), which differ mainly in the arrangement of the optical parts. In these instruments the crystal is set up and adj usted once for all, with the axis of a prominent zone parallel to the axis of either the horizontal or the vertical circle. As a rule, only in this zone can the angles betweenthefaces be measured directly; the positions of all the other faces, which need be observed only once, are fixed by the simultaneous readings of the two circles. These readings, corresponding to the polar distance and azimuth, or latitude and longitude readings of astronomical telescopes, must be plotted on a projection before the symmetry of the crystal is apparent; and laborious calculations are necessary in order to determine the indices of the faces and the angles between them, and the other constants of the crystal, or to test whether any three faces are accurately in a zone.
These disadvantages are overcome by adding still another graduated circle to the instrument, with its axis perpendicular to the axis of the vertical circle, thus forming a three-circle goniometer. With such an instrument measurements may be made in any zone or between any two faces without re-adjusting the crystal; further the troublesome calculations are avoided, and, indeed, the instrument may be used for solving spherical triangles. Different forms of three-circle goniometers have been designed by G. F. H. Smith (1899 and 1904), E. S. Fedorov (1900) and J. F. C. Klein (1900). Besides being used as a one-, two-, or three-circle goniometer for the measurement of the interfaciat angles of crystals, and as a refractometer for determining refractive indices by the prismatic method or by total reflection, Klein's instrument, which is called a polymeter, is fitted with accessory optical apparatus which enables it to be used for examining a crystal in parallel or convergent polarized light and for measuring the optic axial angle.
Goniometers of special construction have been devised for certain purposes; for instance, the inverted horizontal-circle goniometer of H. A. Miers (1903) for measuring crystals during their growth in the mother-liquid. A. E. Tutton (1894) has combined a goniometer with lapidaries' appliances for cutting section-plates and prisms from crystals accurately in any desired direction. The instrument commonly employed for measuring the optic axia) angle of biaxial crystals is really a combination of a goniometer with a polariscope. For the optical investigation of minute crystals under the microscope, various forms of stage-goniometer with one, two or three graduated circles have been constructed. An ordinary microscope fitted with cross-wires and a rotating graduated stage serves the purpose of a goniometer for measuring the plane angles of a crystal face or section, being the same in principle as the contact goniometer.
For fuller descriptions of goniometers reference may be made to the text-books of Crystallography and Mineralogy, especially to P. H. Groth, Physikalische Krystallographie (4th ed., Leipzig, 1905). See also C. Leiss, Die optischen Instrumente der Firma R. Fuess, deren Beschreibung, Justierung undAnwendung (Leipzig, 1899). (L. J. S.)
Note - this article incorporates content from Encyclopaedia Britannica, Eleventh Edition, (1910-1911)
